V6 and Canon Speedlite 600EX-RT

Hi I have a pair of V6s and just purchased a Speedlite 600EX-RT

A simple question that I haven't figured out how to do yet

With a V6 on my Canon 5Dmk3 acting as a transmitter can I trigger the 600EX-RT remotely without the need for it to be connected to a receiving V6. Having read the manual for the Canon Speedlite I can't quite see what I'm doing wrong (if it is possible).

Secondary question is there a profile for the 600EX-RT? I see one for the 600EX - is that the same?

Thanks

John



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